Unclonable Plasmonic Security Labels Achieved by Shadow-Mask-Lithography-Assisted Self-Assembly

Adv Mater. 2016 Mar 23;28(12):2330-6. doi: 10.1002/adma.201505022. Epub 2016 Jan 29.

Abstract

An unclonable plasmonic anti-counterfeiting strategy is demonstrated, which involves the use of molecule-embedded metal@silica core-shell nanoparticles as information carriers. A shadow-mask-lithography-assisted self-assembly is developed for the fabrication of the plasmonic security labels. The produced security labels show multiple sets of coding information that are highly unique, technically unreplicable, and can be robustly decoded by portable microscopes within seconds.

Keywords: core-shell nanoparticles; dark-field and fluorescence microscopy; security labels; self-assembly; surface-enhanced Raman scattering.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Fluorescein / chemistry
  • Gold / chemistry
  • Metal Nanoparticles / chemistry*
  • Metal Nanoparticles / ultrastructure
  • Microscopy, Electron, Transmission
  • Particle Size
  • Photoelectron Spectroscopy
  • Silicon Dioxide / chemistry
  • Silver / chemistry
  • Spectrum Analysis, Raman

Substances

  • Silver
  • Gold
  • Silicon Dioxide
  • Fluorescein