Two novel μ6-O(2-) bridged Co14/Ni14 hydroxamate clusters packed in distorted face-centered cubic patterns

Yanping Zhang; Rui Lv; Jingyao Wang; Linyan Yang; Shengyun Liao; Jinlei Tian; Wen Gu; Xin Liu

doi:10.1039/c5dt03974f

Two novel μ6-O(2-) bridged Co14/Ni14 hydroxamate clusters packed in distorted face-centered cubic patterns

Dalton Trans. 2016 Feb 28;45(8):3247-50. doi: 10.1039/c5dt03974f.

Authors

Yanping Zhang¹, Rui Lv¹, Jingyao Wang¹, Linyan Yang¹, Shengyun Liao¹, Jinlei Tian¹, Wen Gu¹, Xin Liu¹

Affiliation

¹ Department of Chemistry, Collaborative Innovation Center of Chemical Science and Engineering, Nankai University, and Key Laboratory of Advanced Energy Materials Chemistry (MOE), Tianjin 300071, P. R. China. guwen68@nankai.edu.cn liuxin64@nankai.edu.cn.

PMID: 26817593
DOI: 10.1039/c5dt03974f

Abstract

Two novel clusters [Co(μ6-O(2-))(sbha)12(sba)2 (DMF)7(DMA)]·(DMF)8 (1) and [Ni(μ6-O(2-))(sbha)12(sba)2(DMF)8] (2) (sH2bha = 4-bromo-benzohydroximic acid; sHba = 4-bromobenzene carboxylic acid; DMF = N,N-dimethylformamide; DMA = dimethylamine) have been synthesized. The novel body-centred μ6-O(2-) bridged Co14 and Ni14 clusters are packed in distorted face-centered cubic (FCC) patterns with different symmetries. Magnetic studies confirmed the antiferromagnetic exchange interactions between magnetic centers.

Publication types

Research Support, Non-U.S. Gov't