Ethyl chitosan synthesis and quantification of the effects acquired after grafting it on a cotton fabric, using ANOVA statistical analysis

Abstract

Three ethyl chitosans (ECSs) have been prepared using the ethyl chloride (AA) that was obtained in situ. Each ECS was applied on a 100% cotton fabric through a pad-dry-cure technology. Using the ANOVA as statistic method, the wrinkle-proofing effects have been determined varying the concentrations of AA (0.1-2.1mmol) and chitosan (CS) (0.1-2.1mmol). Alkylation and grafting mechanisms have been confirmed by the results of FTIR, (1)H NMR, XPS, SEM, DSC and termogravimetric analyses. The performances of each ECS as wrinkle-proofing agent have been revealed through quantitative methods (taking-up degree, wrinkle-recovering angle, tensile strength and effect's durability). The ECSs confer wrinkle-recovering angle and tensile strength higher than those of the witness sample. Durability of ECSs grafted on cotton have been demonstrated by a good capacity of dyeing with non-specific (acid/anionic and cationic) dyes under severe working conditions (100°C, 60min) and a good antimicrobial capacity.

Keywords: ANOVA; Acetic acid (PubChem CID: 176); C.I. Basic Blue 9 (PubChem CID: 104827); Chitosan (PubChem CID: 71853); Ethanol (PubChem CID: 702); Ethyl chitosan; FTIR; Hydrochloric acid (PubChem CID: 313); Sodium hydroxide (PubChem CID: 14798); Wrinkle-proofing agent; Zinc acetate (PubChem CID: 11192).