Metallic Nanoislands on Graphene as Highly Sensitive Transducers of Mechanical, Biological, and Optical Signals

Nano Lett. 2016 Feb 10;16(2):1375-80. doi: 10.1021/acs.nanolett.5b04821. Epub 2016 Jan 14.

Abstract

This article describes an effect based on the wetting transparency of graphene; the morphology of a metallic film (≤20 nm) when deposited on graphene by evaporation depends strongly on the identity of the substrate supporting the graphene. This control permits the formation of a range of geometries, such as tightly packed nanospheres, nanocrystals, and island-like formations with controllable gaps down to 3 nm. These graphene-supported structures can be transferred to any surface and function as ultrasensitive mechanical signal transducers with high sensitivity and range (at least 4 orders of magnitude of strain) for applications in structural health monitoring, electronic skin, measurement of the contractions of cardiomyocytes, and substrates for surface-enhanced Raman scattering (SERS, including on the tips of optical fibers). These composite films can thus be treated as a platform technology for multimodal sensing. Moreover, they are low profile, mechanically robust, semitransparent and have the potential for reproducible manufacturing over large areas.

Keywords: Graphene; SERS; cardiomyocyte; strain sensor; wearable sensor; wetting transparency.

Publication types

  • Research Support, Non-U.S. Gov't
  • Research Support, U.S. Gov't, Non-P.H.S.

MeSH terms

  • Biosensing Techniques*
  • Graphite / chemistry*
  • Graphite / therapeutic use
  • Humans
  • Mechanical Phenomena
  • Metal Nanoparticles / chemistry*
  • Metal Nanoparticles / therapeutic use
  • Myocytes, Cardiac / pathology
  • Nanoparticles / chemistry
  • Nanospheres / chemistry*
  • Nanospheres / therapeutic use
  • Spectrum Analysis, Raman
  • Surface Properties

Substances

  • Graphite