Para-Selective Cu-Catalyzed C-H Aryloxylation of Electron-Rich Arenes and Heteroarenes

Igors Sokolovs; Edgars Suna

doi:10.1021/acs.joc.5b02728

Para-Selective Cu-Catalyzed C-H Aryloxylation of Electron-Rich Arenes and Heteroarenes

J Org Chem. 2016 Jan 15;81(2):371-9. doi: 10.1021/acs.joc.5b02728. Epub 2015 Dec 29.

Authors

Igors Sokolovs¹, Edgars Suna¹

Affiliation

¹ Latvian Institute of Organic Synthesis , Aizkraukles 21, LV-1006 Riga, Latvia.

PMID: 26700627
DOI: 10.1021/acs.joc.5b02728

Abstract

Cu-catalyzed reaction of phenols with electron-rich arene or heteroarene ligands of unsymmetrical diaryl-λ(3)-iodanes is a key step in the developed one-pot two-step method for intermolecular para-selective C-H aryloxylation of heteroarenes and arenes.

Publication types

Research Support, Non-U.S. Gov't