Use of array of conducting polymers for differentiation of coconut oil products

Talanta. 2016:146:75-82. doi: 10.1016/j.talanta.2015.08.026. Epub 2015 Aug 18.

Abstract

An array of chemiresistors based on conducting polymers was assembled for the differentiation of coconut oil products. The chemiresistor sensors were fabricated through the potentiostatic electrodeposition of polyaniline (PANi), polypyrrole (PPy) and poly(3-methylthiophene) (P-3MTp) on the gap separating two planar gold electrodes set on a Teflon substrate. The change in electrical resistance of the sensors was measured and observed after exposing the array to the headspace of oil samples. The sensor response was found rapid, reversible and reproducible. Different signals were obtained for each coconut oil sample and pattern recognition techniques were employed for the analysis of the data. The developed system was able to distinguish virgin coconut oil (VCO) from refined, bleached & deodorised coconut oil (RBDCO), flavoured VCO, homemade VCO, and rancid VCO.

Keywords: Chemiresistor; Chemometrics; Coconut oil; Conducting polymers; Electronic nose.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Cluster Analysis
  • Coconut Oil
  • Electric Conductivity*
  • Electric Impedance
  • Electrochemistry / instrumentation*
  • Electroplating
  • Food Quality
  • Plant Oils / analysis*
  • Plant Oils / chemistry
  • Polymers / chemistry*
  • Polytetrafluoroethylene / chemistry
  • Principal Component Analysis
  • Volatilization

Substances

  • Plant Oils
  • Polymers
  • Polytetrafluoroethylene
  • Coconut Oil