Synthesis of aromatic ruthenabenzothiophenes via C-H activation of thiophenes

Qingde Zhuo; Zhiyong Chen; Yuhui Yang; Xiaoxi Zhou; Feifei Han; Jun Zhu; Hong Zhang; Haiping Xia

doi:10.1039/c5dt04557f

Synthesis of aromatic ruthenabenzothiophenes via C-H activation of thiophenes

Dalton Trans. 2016 Jan 21;45(3):913-7. doi: 10.1039/c5dt04557f.

Authors

Qingde Zhuo¹, Zhiyong Chen¹, Yuhui Yang¹, Xiaoxi Zhou¹, Feifei Han¹, Jun Zhu¹, Hong Zhang¹, Haiping Xia¹

Affiliation

¹ State Key Laboratory of Physical Chemistry of Solid Surfaces and Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), and College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China. zh@xmu.edu.cn hpxia@xmu.edu.cn.

PMID: 26669561
DOI: 10.1039/c5dt04557f

Abstract

The first ruthenabenzothiophenes have been achieved via the C-H activation of thiophene. These species feature high thermal stability and resistance of a moderate oxidant, which constitute valuable addition to the rare metallaaromatic containing second-row transition metals.

Publication types

Research Support, Non-U.S. Gov't