The impact of doping rates on the morphologies of silver and gold nanowires grown in helium nanodroplets

Phys Chem Chem Phys. 2016 Jan 21;18(3):1451-9. doi: 10.1039/c5cp06248a. Epub 2015 Nov 25.

Abstract

Silver and gold nanowires are grown within superfluid helium nanodroplets and investigated by high resolution electron microscopy after surface deposition. The wire morphologies depend on the rate of metal atom doping in the pickup sequence. While high doping rates result in a polycrystalline face-centered cubic nanowire structure, at lower doping rates the initial fivefold-symmetry seems to be preserved. An explanation for this observation is given by computer simulations, which allow the derivation of timescales for the nanowire growth process inside helium nanodroplets.

Publication types

  • Research Support, Non-U.S. Gov't