High-Performance Energetic Characteristics and Magnetic Properties of a Three-Dimensional Cobalt(II) Metal-Organic Framework Assembled with Azido and Triazole

Xiangyu Liu; Xiaoni Qu; Sheng Zhang; Hongshan Ke; Qi Yang; Quan Shi; Qing Wei; Gang Xie; Sanping Chen

doi:10.1021/acs.inorgchem.5b02196

High-Performance Energetic Characteristics and Magnetic Properties of a Three-Dimensional Cobalt(II) Metal-Organic Framework Assembled with Azido and Triazole

Inorg Chem. 2015 Dec 7;54(23):11520-5. doi: 10.1021/acs.inorgchem.5b02196. Epub 2015 Nov 24.

Authors

Xiangyu Liu^{1

2}, Xiaoni Qu¹, Sheng Zhang¹, Hongshan Ke¹, Qi Yang¹, Quan Shi³, Qing Wei¹, Gang Xie¹, Sanping Chen¹

Affiliations

¹ Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, College of Chemistry and Materials Science, Northwest University , Xi'an 710075, China.
² School of Chemistry and Chemical Engineering, Ningxia University , Yinchuan 750021, China.
³ Dalian Institute of Chemical Physics, Chinese Academy of Sciences , 457 Zhongshan Road, Dalian 116023, China.

PMID: 26599690
DOI: 10.1021/acs.inorgchem.5b02196

Abstract

A three-dimensional metal-organic framework based, high-energy-density compound, [Co5(3-atrz)7(N3)3] (3-atrz = 3-amine-1H-1,2,4-triazole), features superior detonation properties, insensitivity, and thermostability. Magnetic studies show that the compound characterizes the coexistence of remarkable coercivity, metamagnetism, long-range ordering, and relaxation dynamics. The heat-capacity measurement confirms the typical long-range antiferromagnetic ordering below 16 K. This difunctional system exemplifies an effective attempt at developing advanced magnetoenergetic materials.

Publication types

Research Support, Non-U.S. Gov't