Dinuclear lanthanide(III)/zinc(II) complexes with methyl 2-pyridyl ketone oxime

Nikolaos C Anastasiadis; Christina D Polyzou; George E Kostakis; Vlasoula Bekiari; Yanhua Lan; Spyros P Perlepes; Konstantis F Konidaris; Annie K Powell

doi:10.1039/c5dt03663a

Dinuclear lanthanide(III)/zinc(II) complexes with methyl 2-pyridyl ketone oxime

Dalton Trans. 2015 Dec 14;44(46):19791-5. doi: 10.1039/c5dt03663a.

Authors

Nikolaos C Anastasiadis¹, Christina D Polyzou¹, George E Kostakis², Vlasoula Bekiari³, Yanhua Lan⁴, Spyros P Perlepes⁵, Konstantis F Konidaris⁶, Annie K Powell⁷

Affiliations

¹ Institute of Nanotechnology, Karlsruhe Institute of Technology, Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen, Germany. konstantis.konidaris@gmail.com and Department of Chemistry, University of Patras, GR-265 04 Patras, Greece.
² Institute of Nanotechnology, Karlsruhe Institute of Technology, Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen, Germany. konstantis.konidaris@gmail.com and Department of Chemistry, School of Life Sciences, University of Sussex, Brighton BN1 9QJ, UK.
³ Department of Aquaculture, Technological Educational Institute of Western Greece, GR-30200 Messolonghi, Greece.
⁴ Institute of Inorganic Chemistry, Karlsruhe Institute of Technology, Engesserstrasse 15, 76131 Karlsruhe, Germany. annie.powell@kit.edu.
⁵ Department of Chemistry, University of Patras, GR-265 04 Patras, Greece.
⁶ Institute of Nanotechnology, Karlsruhe Institute of Technology, Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen, Germany. konstantis.konidaris@gmail.com.
⁷ Institute of Nanotechnology, Karlsruhe Institute of Technology, Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen, Germany. konstantis.konidaris@gmail.com and Institute of Inorganic Chemistry, Karlsruhe Institute of Technology, Engesserstrasse 15, 76131 Karlsruhe, Germany. annie.powell@kit.edu.

PMID: 26537457
DOI: 10.1039/c5dt03663a

Abstract

The first use of methyl 2-pyridyl ketone oxime (mpkoH) in zinc(II)/lanthanide(III) chemistry leads to the [ZnLn(mpko)3(mpkoH)3](ClO4)2 and [ZnLn(NO3)2(mpko)3(mpkoH)] families of dinuclear Zn(II)Ln(III) complexes displaying blue-green, ligand-based photoluminescence; the Zn(II)Dy(III) compound shows field-induced relaxation of magnetization.

Publication types

Research Support, Non-U.S. Gov't