Synthesis of a Novel Highly Oleophilic and Highly Hydrophobic Sponge for Rapid Oil Spill Cleanup

ACS Appl Mater Interfaces. 2015 Nov 18;7(45):25326-33. doi: 10.1021/acsami.5b07504. Epub 2015 Nov 5.

Abstract

A highly hydrophobic and highly oleophilic sponge was synthesized by simple vapor-phase deposition followed by polymerization of polypyrrole followed by modification with palmitic acid. The prepared sponge shows high absorption capacity in the field of separation and removal of different oil spills from water surface and was able to emulsify oil/water mixtures. The sponge can be compressed repeatedly without collapsing. Therefore, absorbed oils can be readily collected by simple mechanical squeezing of the sponge. The prepared hydrophobic sponge can collect oil from water in both static and turbulent conditions. The proposed method is simple and low cost for the manufacture of highly oleophilic and highly hydrophobic sponges, which can be successfully used for effective oil-spill cleanup and water filtration.

Keywords: continuous separation; high hydrophobicity; high oleophilicity; hydrophobic sponge; oil-spill cleanup.

Publication types

  • Research Support, Non-U.S. Gov't