Chitosan-Based Aerogel Membrane for Robust Oil-in-Water Emulsion Separation

ACS Appl Mater Interfaces. 2015 Nov 11;7(44):24957-62. doi: 10.1021/acsami.5b08705. Epub 2015 Oct 30.

Abstract

Here, we demonstrate direct recovery of water from stable emulsion waste using aerogel membrane. Chitosan-based gel was transformed into highly porous aerogel membrane using bio-origin genipin as cross-linking agent. Aerogel membranes were characterized for their morphology using SEM, chemical composition by FTIR and solid-UV. Further, aerogel was tested for recovery of high quality water from oil spill sample collected from ship breaking yard. High quality (with >99% purity) water was recovered with a flux rate of >600 L·m(-2)·h(-1)·bar(-1). After repeated use, aerogel membranes were tested for greener disposal possibilities by biodegrading membrane in soil.

Keywords: aerogel membrane; biopolymer; emulsion; oil−water separation; wastewater.

MeSH terms

  • Biocompatible Materials / chemistry
  • Chitosan / chemistry*
  • Cross-Linking Reagents / chemistry
  • Emulsions / chemistry*
  • Membranes, Artificial
  • Microscopy, Electron, Scanning
  • Oils / chemistry*
  • Petroleum Pollution*
  • Polymers / chemistry
  • Porosity
  • Spectrophotometry, Ultraviolet
  • Spectroscopy, Fourier Transform Infrared
  • Thermogravimetry
  • Wastewater
  • Water / chemistry*
  • Water Purification / methods

Substances

  • Biocompatible Materials
  • Cross-Linking Reagents
  • Emulsions
  • Membranes, Artificial
  • Oils
  • Polymers
  • Waste Water
  • Water
  • Chitosan