Abstract
[Ni(L(1))Fe((t)BuNC)4](PF6)2 is a robust Ni(II)Fe(II) complex that undergoes a reversible one-electron reduction. Spectroscopic and theoretical studies show that [Ni(L(1))Fe((t)BuNC)4](+) is an unprecedented Ni(I)Fe(II) species that reproduces the electronic configuration of the Ni-L state of the [NiFe] hydrogenases.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Catalytic Domain
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Coordination Complexes / chemical synthesis
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Coordination Complexes / chemistry*
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Ferrous Compounds / chemical synthesis
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Ferrous Compounds / chemistry*
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Hydrogenase / chemistry*
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Models, Chemical
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Models, Molecular
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Molecular Mimicry
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Nickel / chemistry
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Oxidation-Reduction
Substances
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Coordination Complexes
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Ferrous Compounds
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Nickel
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nickel-iron hydrogenase
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Hydrogenase