Communication: Broadband and ultrasensitive femtosecond time-resolved circular dichroism spectroscopy

J Chem Phys. 2015 Sep 28;143(12):121102. doi: 10.1063/1.4932229.

Abstract

We report the development of broadband and sensitive time-resolved circular dichroism (TRCD) spectroscopy by exploiting optical heterodyne detection. Using this method, transient CD signals of submillidegree level can be detected over the spectral range of 415-730 nm. We also demonstrate that the broadband measurement with the aid of singular value decomposition enables the discrimination of genuine TRCD signals from artificial optical-anisotropy, such as linear birefringence and linear dichroism, induced by photoexcitation.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Circular Dichroism / methods*
  • Computer Simulation
  • Equipment Design
  • Models, Chemical
  • Photochemical Processes
  • Ruthenium Compounds / chemistry

Substances

  • Ruthenium Compounds