Visible-light-promoted chloramination of olefins with N-chlorosulfonamide as both nitrogen and chlorine sources

Org Biomol Chem. 2015 Nov 7;13(41):10295-8. doi: 10.1039/c5ob01725d.

Abstract

A visible-light-promoted chloramination of olefins is reported. N-Chlorosulfonamides serve as both nitrogen and chlorine sources. These reactions provide a simple, efficient, regioselective, and atom-economical method for the preparation of vicinal haloamine derivatives under mild reaction conditions. A variety of olefins were tolerated, and chloramination products were obtained in good yields.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Alkenes / chemistry*
  • Amination / radiation effects
  • Chloramines / chemical synthesis*
  • Chloramines / chemistry
  • Chlorine / chemistry*
  • Light*
  • Molecular Structure
  • Nitrogen / chemistry*
  • Sulfonamides / chemistry*

Substances

  • Alkenes
  • Chloramines
  • N-chlorosulfonamide
  • Sulfonamides
  • Chlorine
  • Nitrogen