Multifunctional Polymer Nanofibers: UV Emission, Optical Gain, Anisotropic Wetting, and High Hydrophobicity for Next Flexible Excitation Sources

ACS Appl Mater Interfaces. 2015 Oct 7;7(39):21907-12. doi: 10.1021/acsami.5b06483. Epub 2015 Sep 24.

Abstract

The use of UV light sources is highly relevant in many fields of science, being directly related to all those detection and diagnosis procedures that are based on fluorescence spectroscopy. Depending on the specific application, UV light-emitting materials are desired to feature a number of opto-mechanical properties, including brightness, optical gain for being used in laser devices, flexibility to conform with different lab-on-chip architectures, and tailorable wettability to control and minimize their interaction with ambient humidity and fluids. In this work, we introduce multifunctional, UV-emitting electrospun fibers with both optical gain and greatly enhanced anisotropic hydrophobicity compared to films. Fibers are described by the onset of a composite wetting state, and their arrangement in uniaxial arrays further favors liquid directional control. The low gain threshold, optical losses, plastic nature, flexibility, and stability of these UV-emitting fibers make them interesting for building light-emitting devices and microlasers. Furthermore, the anisotropic hydrophobicity found is strongly synergic with optical properties, reducing interfacial interactions with liquids and enabling smart functional surfaces for droplet microfluidic and wearable applications.

Keywords: UV light sources; dye-doped fibers; electrospinning; optical gain; plastic optical amplifier; polymer nanofibers.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Electrochemical Techniques
  • Hydrophobic and Hydrophilic Interactions
  • Luminescent Agents / chemistry*
  • Nanofibers / chemistry*
  • Polymers / chemistry*
  • Ultraviolet Rays
  • Wettability

Substances

  • Luminescent Agents
  • Polymers