Crystal structure of 2-methyl-N-{[2-(pyri-din-2-yl)eth-yl]carbamo-thio-yl}benzamide

Acta Crystallogr E Crystallogr Commun. 2015 Aug 6;71(Pt 9):o636. doi: 10.1107/S2056989015013559. eCollection 2015 Sep 1.

Abstract

In the title compound, C16H17N3OS, a benzoyl thio-urea derivative, the planes of the pyridine and benzene rings are inclined to one another by 66.54 (9)°. There is an intra-molecular N-H⋯O hydrogen bond present forming an S(6) ring motif. In the crystal, mol-ecules are linked via pairs of N-H⋯N hydrogen bonds, forming inversion dimers, which are reinforced by pairs of C-H⋯S hydrogen bonds. The dimers are linked via C-H⋯π inter-actions, forming ribbons along [010].

Keywords: benzamide; carbonyl thio­urea; crystal structure; hydrogen bonding; inversion dimers.