Crystal structure of (±)-1-({[4-(all-yloxy)phen-yl]sulfan-yl}meth-yl)-2-(di-phenyl-thio-phosphor-yl)ferrocene

Audric Michelot; Stéphanie Sarda; Jean-Claude Daran; Eric Deydier; Eric Manoury

doi:10.1107/S2056989015013560

Crystal structure of (±)-1-({[4-(all-yloxy)phen-yl]sulfan-yl}meth-yl)-2-(di-phenyl-thio-phosphor-yl)ferrocene

Acta Crystallogr E Crystallogr Commun. 2015 Jul 29;71(Pt 8):972-5. doi: 10.1107/S2056989015013560. eCollection 2015 Aug 1.

Authors

Audric Michelot¹, Stéphanie Sarda², Jean-Claude Daran³, Eric Deydier¹, Eric Manoury⁴

Affiliations

¹ Université de Toulouse, UPS, INPT, F-31077 Toulouse Cedex 4, France ; CNRS, LCC (Laboratoire de Chimie de Coordination), IUT, Département de Chimie, avenue Georges Pompidou, BP258, 81104 Castres, France.
² CIRIMAT, équipe PPB, Université Paul Sabatier, ENSIACET - Bureau 2-r1-5, 4 Allée Emile Monso BP 44362, 31432 Toulouse Cedex 4, France.
³ Laboratoire de Chimie de Coordination, 205 route de Narbonne, 31077 Toulouse, Cedex 04, France.
⁴ Laboratoire de Chimie de Coordination, 205 route de Narbonne, 31077 Toulouse, Cedex 04, France ; Université de Toulouse, UPS, INPT, F-31077 Toulouse Cedex 4, France.

Abstract

The title compound, [Fe(C5H5)(C27H24OPS2)], is built up from a ferrocene moiety substituted in the 1- and 2-positions by {[4-(all-yloxy)phen-yl]sulfan-yl}methyl and di-phenyl-thio-phosphoryl groups, respectively. The two S atoms lie on opposite sides of the cyclo-penta-dienyl ring plane to which they are attached. In the crystal, C-H⋯S hydrogen bonds link the mol-ecules into a ribbon running parallel to the (-110) plane. C-H⋯π inter-actions link the ribbons to form a three-dimensional network.

Keywords: asymmetric catalysis; crystal structure; ferrocenyl ligands; planar chirality.