Nuclear Overhauser effects and conformations of branched trisaccharide methyl beta-glycosides that contain a 2,3-disubstituted galactose residue

G M Lipkind; A S Shashkov; O A Nechaev; V I Torgov; V N Shibaev; N K Kochetkov

doi:10.1016/0008-6215(89)85085-2

Nuclear Overhauser effects and conformations of branched trisaccharide methyl beta-glycosides that contain a 2,3-disubstituted galactose residue

Carbohydr Res. 1989 Dec 21;195(1):27-37. doi: 10.1016/0008-6215(89)85085-2.

Authors

G M Lipkind¹, A S Shashkov, O A Nechaev, V I Torgov, V N Shibaev, N K Kochetkov

Affiliation

¹ N. D. Zelinsky Institute of Organic Chemistry, Academy of Sciences of the U.S.S.R., Moscow.

PMID: 2636043
DOI: 10.1016/0008-6215(89)85085-2

Abstract

On the basis of the n.O.e. data and theoretical calculations, it was found that less than 90% of one conformer was present in aqueous solution for each of a series of trisaccharide methyl beta-glycosides with a 2,3-disubstituted galactose residue.

MeSH terms

Carbohydrate Conformation
Carbohydrate Sequence
Galactose / analogs & derivatives*
Glycosides*
Magnetic Resonance Spectroscopy
Molecular Sequence Data
Trisaccharides*

Substances

Glycosides
Trisaccharides
Galactose