Two nanocage-based metal-organic frameworks with mixed-cluster SBUs and CO2 sorption selectivity

Bo Liu; Wei-Ping Wu; Lei Hou; Zhi-Sen Li; Yao-Yu Wang

doi:10.1021/acs.inorgchem.5b00987

Two nanocage-based metal-organic frameworks with mixed-cluster SBUs and CO2 sorption selectivity

Inorg Chem. 2015 Sep 21;54(18):8937-42. doi: 10.1021/acs.inorgchem.5b00987. Epub 2015 Sep 10.

Authors

Bo Liu¹, Wei-Ping Wu^{1

2}, Lei Hou¹, Zhi-Sen Li¹, Yao-Yu Wang¹

Affiliations

¹ Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of the Ministry of Education, Shaanxi Key Laboratory of Physico-Inorganic Chemistry, College of Chemistry & Materials Science, Northwest University , Xi'an 710069, P. R. China.
² Institute of Functional Materials, College of Chemistry and Pharmaceutical Engineering, Sichuan University of Science & Engineering , Zigong 643000, P. R. China.

PMID: 26355678
DOI: 10.1021/acs.inorgchem.5b00987

Abstract

Two nanocage-based metal-organic frameworks respectively built on two and three types of clusters with diisophthalate ligand were constructed, displaying unprecedented (3,4,6)-connected nets, unusual nanocages, and new bipaddle-wheel tetranuclear cluster, as well as highly selective CO2 capture.

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Adsorption*
Carbon Dioxide / chemistry*
Manganese / chemistry
Organometallic Compounds / chemistry*
Surface Properties
Zinc / chemistry

Substances

Organometallic Compounds
Carbon Dioxide
Manganese
Zinc