Double interpenetration in a chiral three-dimensional magnet with a (10,3)-a structure

Thais Grancha; Marta Mon; Francesc Lloret; Jesús Ferrando-Soria; Yves Journaux; Jorge Pasán; Emilio Pardo

doi:10.1021/acs.inorgchem.5b01738

Double interpenetration in a chiral three-dimensional magnet with a (10,3)-a structure

Inorg Chem. 2015 Sep 21;54(18):8890-2. doi: 10.1021/acs.inorgchem.5b01738. Epub 2015 Aug 31.

Authors

Thais Grancha¹, Marta Mon¹, Francesc Lloret¹, Jesús Ferrando-Soria¹, Yves Journaux², Jorge Pasán³, Emilio Pardo¹

Affiliations

¹ Departament de Química Inorgànica, Instituto de Ciencia Molecular (ICMOL), Universitat de València , 46980 Paterna, València, Spain.
² Institut Parisien de Chimie Moléculaire, Université Pierre et Marie Curie-Paris 6, UMR 7201 , F-75252 Paris, France.
³ Laboratorio de Rayos X y Materiales Moleculares, Departamento de Física, Universidad de La Laguna , E-38201 Tenerife, Spain.

PMID: 26322529
DOI: 10.1021/acs.inorgchem.5b01738

Abstract

A unique chiral three-dimensional magnet with an overall racemic double-interpenetrated (10,3)-a structure of the formula [(S)-(1-PhEt)Me3N]4[Mn4Cu6(Et2pma)12](DMSO)3]·3DMSO·5H2O (1; Et2pma = N-2,6-diethylphenyloxamate) has been synthesized by the self-assembly of a mononuclear copper(II) complex acting as a metalloligand toward Mn(II) ions in the presence of a chiral cationic auxiliary, constituting the first oxamato-based chiral coordination polymer exhibiting long-range magnetic ordering.