Nitrogen-doped porous carbon derived from biomass waste for high-performance supercapacitor

Bioresour Technol. 2015 Dec:197:137-42. doi: 10.1016/j.biortech.2015.07.100. Epub 2015 Aug 1.

Abstract

High capacitance property and low cost are the pivotal requirements for practical application of supercapacitor. In this paper, a low cost and high capacitance property nitrogen-doped porous carbon with high specific capacitance is prepared. The as-prepared nitrogen-doped porous carbon employing potato waste residue (PWR) as the carbon source, zinc chloride (ZnCl2) as the activating agent and melamine as nitrogen doping agent. The morphology and structure of the carbon materials are studied by scanning electron microscopy (SEM), N2 adsorption/desorption, X-ray diffraction (XRD) and Raman spectra. The surface area of the nitrogen-doped carbon which prepared under 700°C is found to be 1052m(2)/g, and the specific capacitance as high as 255Fg(-1) in 2M KOH electrolyte is obtained utilize the carbon as electrode materials. The electrode materials also show excellent cyclability with 93.7% coulombic efficiency at 5Ag(-1) current density of for 5000cycles.

Keywords: Nitrogen-doped porous carbon; Potato waste residue; Supercapacitor.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Biomass*
  • Carbon / chemistry*
  • Chlorides / chemistry
  • Electric Capacitance
  • Electrodes
  • Nitrogen / chemistry*
  • Porosity
  • Refuse Disposal / methods*
  • Solanum tuberosum / chemistry*
  • Zinc Compounds / chemistry

Substances

  • Chlorides
  • Zinc Compounds
  • Carbon
  • zinc chloride
  • Nitrogen