Enhancing the Thermal Stability of Solution-Processed Small-Molecule Semiconductor Thin Films Using a Flexible Linker Approach

Adv Mater. 2015 Oct 7;27(37):5541-6. doi: 10.1002/adma.201501826. Epub 2015 Aug 25.

Abstract

Using flexible aliphatic chains to link conjugated molecular semiconductors affords a polymeric material that possesses defined conjugated segments but extended covalent connectivity, which enhances crystallinity and thermal stability in field-effect transistors and bulk heterojunction solar-cell devices when used as an additive.

Keywords: crystallinity; morphology; organic solar cells; thin-film transistors.