Nanoscale Heterostructures Based on Fe2O3@WO3-x Nanoneedles and Their Direct Integration into Flexible Transducing Platforms for Toluene Sensing

ACS Appl Mater Interfaces. 2015 Aug 26;7(33):18638-49. doi: 10.1021/acsami.5b05081. Epub 2015 Aug 14.

Abstract

Nanoscale heterostructures based on WO3-x nanoneedles functionalized with Fe2O3 nanoparticles are integrated directly into flexible polymer-based transducing platforms via aerosol-assisted chemical vapor deposition. Results demonstrate that the incorporation of Fe2O3 nanoparticles at the surface of WO3-x nanoneedles enhances the electronic and sensing properties of WO3-x, providing a 6-fold increase in sensitivity to toluene and low cross-sensitivity to hydrogen and ethanol. These enhanced-sensing properties are comparable to those obtained via functionalization with precious metal (Pt) nanoparticles, which are commonly used to enhance sensor performance.

Keywords: AACVD; ferric oxide; flexible gas sensors; toluene; tungsten oxide.

Publication types

  • Research Support, Non-U.S. Gov't