Models based on ultraviolet spectroscopy, polyphenols, oligosaccharides and polysaccharides for prediction of wine astringency

Food Chem. 2016 Jan 1:190:357-363. doi: 10.1016/j.foodchem.2015.05.062. Epub 2015 May 15.

Abstract

Astringency elicited by tannins is usually assessed by tasting. Alternative methods involving tannin precipitation have been proposed, but they remain time-consuming. Our goal was to propose a faster method and investigate the links between wine composition and astringency. Red wines covering a wide range of astringency intensities, assessed by sensory analysis, were selected. Prediction models based on multiple linear regression (MLR) were built using UV spectrophotometry (190-400 nm) and chemical analysis (enological analysis, polyphenols, oligosaccharides and polysaccharides). Astringency intensity was strongly correlated (R(2) = 0.825) with tannin precipitation by bovine serum albumin (BSA). Wine absorbances at 230 nm (A230) proved more suitable for astringency prediction (R(2) = 0.705) than A280 (R(2) = 0.56) or tannin concentration estimated by phloroglucinolysis (R(2) = 0.59). Three variable models built with A230, oligosaccharides and polysaccharides presented high R(2) and low errors of cross-validation. These models confirmed that polysaccharides decrease astringency perception and indicated a positive relationship between oligosaccharides and astringency.

Keywords: A230; Astringency; Bovine serum albumine; Multiple linear regression; Oligosaccharides; Polyphenols; Polysaccharides; Sensory.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Oligosaccharides / analysis*
  • Polyphenols / analysis*
  • Polysaccharides / analysis*
  • Serum Albumin, Bovine / chemistry
  • Spectrophotometry, Ultraviolet
  • Tannins / chemistry
  • Taste Perception
  • Wine / analysis*

Substances

  • Oligosaccharides
  • Polyphenols
  • Polysaccharides
  • Tannins
  • Serum Albumin, Bovine