Over 1-year period, 13 polycyclic aromatic hydrocarbons (PAHs) associated with particulate matter PM10 have been monitored for the first time in the atmosphere of Ciudad Real, situated at the central-southern Spain. PM10-bound PAHs were collected using a high-volume sampler from autumn 2012 to summer 2013 and were analyzed by HPLC with fluorescence detector. The most abundant PAHs were pyrene, chrysene, benzo[b]fluoranthene, dibenzo[a,h]anthracene and benzo[g,h,i]perylene. The ∑PAH concentrations in Ciudad Real were 888, 368, 259 and 382 pg m(-3) for winter, spring, summer and autumn seasons, respectively. The diurnal variation of PAH was also investigated presenting the highest concentrations during the evening (19:00-23:00). Benzo[a]pyrene concentrations ranged from 2.4 to 110 pg m(-3), these values are lower than the target value proposed by the European legislation, 1 ng m(-3). Diagnostic ratios were used to identify potential sources of PAHs. Results suggest that vehicle emissions are the major source of identified PAHs, with a higher contribution of diesel engines although other anthropogenic sources could also have an impact on the PAH levels.
Keywords: Benzo[a]pyrene; Ciudad Real; HPLC; High-volume sampler; PAH; PM10.