Renaissance for low shrinking resins: all-in-one solution by bi-functional vinylcyclopropane-amides

Chem Commun (Camb). 2015 Jul 28;51(59):11899-902. doi: 10.1039/c5cc03901k.

Abstract

A low volume shrinking vinylcyclopropane (VCP) monomer, showing both a high reactivity and a low viscosity, was obtained by applying a sterically hindered and isomeric spacer element, incorporating intermolecular amide hydrogen bonds. The resulting properties locate this VCP system in a pronounced range that so far no other efficient and radical polymerizable resin could enter.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Amides / chemistry*
  • Cyclopentanes / chemistry*
  • Hydrogen Bonding
  • Molecular Structure
  • Resins, Synthetic / chemistry*
  • Solutions
  • Vinyl Compounds / chemistry*

Substances

  • Amides
  • Cyclopentanes
  • Resins, Synthetic
  • Solutions
  • Vinyl Compounds