Abstract
Vinyliodide reacts chemoselectively under Heck-Mizoroki conditions with terminal alkenes, including vinylboronate esters, to give dienes. The resulting dienylboronates undergo Suzuki-Miyaura couplings with aryl, heteroaryl and alkenyl halides to access dienes and trienes.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Alkenes / chemical synthesis*
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Alkenes / chemistry
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Alkynes / chemical synthesis*
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Alkynes / chemistry
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Catalysis
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Palladium / chemistry
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Polyenes / chemical synthesis*
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Polyenes / chemistry
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Stereoisomerism
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Vinyl Compounds / chemical synthesis
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Vinyl Compounds / chemistry*
Substances
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Alkenes
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Alkynes
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Polyenes
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Vinyl Compounds
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vinylboronate ester
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Palladium