Spectral, morphological, linear and nonlinear optical properties of nanostructured benzimidazole metal complex thin films

P A Praveen; R Ramesh Babu; K Jothivenkatachalam; K Ramamurthi

doi:10.1016/j.saa.2015.05.074

Spectral, morphological, linear and nonlinear optical properties of nanostructured benzimidazole metal complex thin films

Spectrochim Acta A Mol Biomol Spectrosc. 2015 Nov 5:150:280-9. doi: 10.1016/j.saa.2015.05.074. Epub 2015 May 29.

Authors

P A Praveen¹, R Ramesh Babu², K Jothivenkatachalam³, K Ramamurthi⁴

Affiliations

¹ Crystal Growth and Thin film Laboratory, Department of Physics, Bharathidasan University, Tiruchirappalli 620 024, Tamil Nadu, India.
² Crystal Growth and Thin film Laboratory, Department of Physics, Bharathidasan University, Tiruchirappalli 620 024, Tamil Nadu, India. Electronic address: rampap2k@yahoo.co.in.
³ Department of Chemistry, Anna University-BIT Campus, Tiruchirappalli 620 024, Tamil Nadu, India.
⁴ Crystal Growth and Thin film Laboratory, Department of Physics and Nanotechnology, SRM University, Kattankulathur 603 203, Kancheepuram, Tamil Nadu, India.

PMID: 26056978
DOI: 10.1016/j.saa.2015.05.074

Abstract

Metal organic materials are widely investigated to find their suitability for nonlinear optical applications due to the advantage of combined organic and inorganic properties. In this work benzimidazole based metal organic thin films of dichlorobis (1H-Benzimidazole) Co(II) and dichlorobis (1H-Benzimidazole) Cu(II) were deposited by chemical bath deposition method. The deposited films were annealed at 100, 150 and 200 °C to investigate the effect of annealing on the properties of thin films. Surface homogeneity of the films was increased with the annealing temperature due to the surface diffusion of the films and the same was evidently shown by Raman spectroscopy and Atomic Force Microscopy studies. But annealing the films at 200 °C yielded bulk patches on the surface due to the distortion of molecules. Linear and nonlinear optical properties of the films annealed at 150 °C showed relatively higher transmittance and improved nonlinear optical properties than the other as prepared and annealed samples.

Keywords: Annealing; CW Z-scan; Metal organic thin films; Nonlinear optical properties; Optical limiting.

Publication types

Research Support, Non-U.S. Gov't