Crystal structure of 4-meth-oxy-N-[(pyrrolidin-1-yl)carbo-thio-yl]benzamide

Khairi Suhud; Lee Yook Heng; Siti Aishah Hasbullah; Musa Ahmad; Mohammad B Kassim

doi:10.1107/S2056989015003813

Crystal structure of 4-meth-oxy-N-[(pyrrolidin-1-yl)carbo-thio-yl]benzamide

Acta Crystallogr E Crystallogr Commun. 2015 Mar 4;71(Pt 4):o225-6. doi: 10.1107/S2056989015003813. eCollection 2015 Apr 1.

Authors

Khairi Suhud¹, Lee Yook Heng², Siti Aishah Hasbullah², Musa Ahmad³, Mohammad B Kassim⁴

Affiliations

¹ School of Chemical Sciences and Food Technology, Faculty of Science and Technology, Universiti Kebangsaan Malaysia, 43600 Selangor, Malaysia ; Department of Chemistry, Mathematics & Natural Science Faculty, Universitas Syiah Kuala, Banda Aceh, 23111, Indonesia.
² School of Chemical Sciences and Food Technology, Faculty of Science and Technology, Universiti Kebangsaan Malaysia, 43600 Selangor, Malaysia.
³ Chemical Technology Program, Faculty of Science Technology, Universiti Sains Islam Malaysia, Bandar Baru Nilai, 71800 Nilai, Negeri Sembilan, Malaysia.
⁴ School of Chemical Sciences and Food Technology, Faculty of Science and Technology, Universiti Kebangsaan Malaysia, 43600 Selangor, Malaysia ; Fuel Cell Institute, Universiti Kebangsaan Malaysia, 43600 Selangor, Malaysia.

Abstract

In the title compound, C13H16N2O2S, the pyrrolidine ring has a twisted conformation on the central -CH2-CH2- bond. Its mean plane is inclined to the 4-meth-oxy-benzoyl ring by 72.79 (15)°. In the crystal, mol-ecules are linked by N-H⋯O and C-H⋯O hydrogen bonds to the same O-atom acceptor, forming chains along [001]. The chains are linked via slipped parallel π-π inter-actions [inter-centroid distance = 3.7578 (13) Å], forming undulating slabs parallel to (100).

Keywords: benzamide; benzoylthiourea; crystal structure; hydrogen bonding; pyrrolidine; thiourea.