Crystal structure of catena-poly[[di-aqua-cadmium(II)]-μ-3,3'-(1,3-phenyl-ene)diacrylato]

Xiao-Ping Zhang; Xin Chen; Kun-Lin Huang

doi:10.1107/S2056989015005411

Crystal structure of catena-poly[[di-aqua-cadmium(II)]-μ-3,3'-(1,3-phenyl-ene)diacrylato]

Acta Crystallogr E Crystallogr Commun. 2015 Mar 21;71(Pt 4):m91-2. doi: 10.1107/S2056989015005411. eCollection 2015 Apr 1.

Authors

Xiao-Ping Zhang¹, Xin Chen¹, Kun-Lin Huang¹

Affiliation

¹ Key Laboratory of Green Synthesis and Applications, College of Chemistry, Chongqing Normal University, Chongqing 401331, People's Republic of China.

Abstract

In the crystal of the title polymeric complex, [Cd(C12H8O4)(H2O)2] n , the Cd(II) cation, located on a twofold rotation axis, is coordinated by two water mol-ecules and chelated by two phenyl-enediacrylate anions (mpda) in a distorted octa-hedral geometry. The mpda anions bridge the Cd(II) cations, forming helical chains propagating along the c-axis direction. The mpba anion has twofold symmetry with two benzene C atoms located on the twofold rotation axis. In the crystal, O-H⋯O hydrogen bonds link the polymeric helical chains into a three-dimensional supra-molecular architecture.

Keywords: V-shaped ligand; cadmium; chiral coordination polymer; crystal structure; helical chain.