A heterobimetallic [Mn₅(II)Cu₅(II)] nanowheel modulated by a flexible bis-oxamate type ligand

Dalton Trans. 2015 Jun 28;44(24):10939-42. doi: 10.1039/c5dt00996k. Epub 2015 May 26.

Abstract

The synthesis, crystal structure and preliminary magnetic characterization of a new heterobimetallic [Mn₅(II)Cu₅(II)] wheel containing a flexible bis-oxamate type ligand are described. This decanuclear compound exhibits a relatively strong intra-wheel antiferromagnetic interaction leading to a ground spin state S = 10.