Crystal structure of 2-methyl-N-[(4-methyl-pyridin-2-yl)carbamo-thio-yl]benzamide

Acta Crystallogr E Crystallogr Commun. 2015 Apr 30;71(Pt 5):o356. doi: 10.1107/S2056989015007860. eCollection 2015 May 1.

Abstract

In the title compound, C15H15N3OS, there is an intra-molecular N-H⋯O hydrogen bond and an intra-molecular C-H⋯S hydrogen bond involving the C=O and C=S bonds which lie on opposite sides of the mol-ecule. The mol-ecule is non-planar with the benzene and pyridine rings being inclined to one another by 26.86 (9)°. In the crystal, mol-ecules are linked by pairs of N-H⋯S hydrogen bonds, forming inversion dimers with an R 2 (2)(8) ring motif. The dimers are linked via C-H⋯S hydrogen bonds, forming slabs parallel to the bc plane.

Keywords: benzamide group; carbonyl thio­urea; crystal structure; ortho position.