Reduced graphene oxide/carbon double-coated 3-D porous ZnO aggregates as high-performance Li-ion anode materials

Sungun Wi; Hyungsub Woo; Sangheon Lee; Joonhyeon Kang; Jaewon Kim; Subin An; Chohui Kim; Seunghoon Nam; Chunjoong Kim; Byungwoo Park

doi:10.1186/s11671-015-0902-7

Reduced graphene oxide/carbon double-coated 3-D porous ZnO aggregates as high-performance Li-ion anode materials

Nanoscale Res Lett. 2015 May 1:10:204. doi: 10.1186/s11671-015-0902-7. eCollection 2015.

Authors

Affiliations

¹ WCU Hybrid Materials Program, Department of Materials Science and Engineering, Research Institute of Advanced Materials, Seoul National University, Seoul, 151-744 South Korea.
² School of Materials Science and Engineering, Chungnam National University, Daejeon, 305-764 South Korea.

Abstract

The reduced graphene oxide (RGO)/carbon double-coated 3-D porous ZnO aggregates (RGO/C/ZnO) have been successfully synthesized as anode materials for Li-ion batteries with excellent cyclability and rate capability. The mesoporous ZnO aggregates prepared by a simple solvothermal method are sequentially modified through distinct carbon-based double coating. These novel architectures take unique advantages of mesopores acting as space to accommodate volume expansion during cycling, while the conformal carbon layer on each nanoparticle buffering volume changes, and conductive RGO sheets connect the aggregates to each other. Consequently, the RGO/C/ZnO exhibits superior electrochemical performance, including remarkably prolonged cycle life and excellent rate capability. Such improved performance of RGO/C/ZnO may be attributed to synergistic effects of both the 3-D porous nanostructures and RGO/C double coating.

Keywords: 3-D porous ZnO aggregate; Double coating; Li-ion battery; Reduced graphene oxide.