Sol-gel microspheres doped with glycerol: a structural insight in light of forthcoming applications in the polyurethane foam industry

Rosaria Ciriminna; Alexandra Fidalgo; Laura M Ilharco; Mario Pagliaro

doi:10.1002/open.201500023

Sol-gel microspheres doped with glycerol: a structural insight in light of forthcoming applications in the polyurethane foam industry

ChemistryOpen. 2015 Apr;4(2):78. doi: 10.1002/open.201500023.

Authors

Rosaria Ciriminna¹, Alexandra Fidalgo², Laura M Ilharco², Mario Pagliaro¹

Affiliations

¹ Istituto per lo Studio dei Materiali Nanostrutturati (CNR via U. La Malfa 153, 90146, Palermo, (Italy).
² Centro de Química-Física Molecular and Institute of Nanoscience & Nanotechnology (IN, Instituto Superior Técnico Complexo I, Av. Rovisco Pais 1, 1049-001, Lisboa, (Portugal).

Abstract

Invited for this months cover are the groups of Professor Mario Pagliaro at the Istituto per lo Studio dei Materiali Nanostrutturati in Palermo and Professor Laura Ilharco at the Instituto Superior Técnico in Lisboa. The cover picture shows a- GreenCaps- microcapsule breaking and releasing encapsulated glycerol after the organosilica microspheres are sprayed from a pressurized polyurethane foam can. This shows how glycerol acts as a solid curing agent, promoting crosslinking of partially polymerized diphenylmethane diisocyanate. For more details, see the Full Paper on p. 120 ff.