3D hydrodynamic interactions lead to divergences in 2D diffusion

J Phys Condens Matter. 2015 May 20;27(19):194113. doi: 10.1088/0953-8984/27/19/194113. Epub 2015 Apr 29.

Abstract

We investigate the influence of 3D hydrodynamic interactions on confined colloidal suspensions, where only the colloids are restricted to one or two dimensions. In the absence of static interactions among the colloids, i.e., an ideal gas of colloidal particles with a finite hydrodynamic radius, we find a divergent collective diffusion coefficient. The origin of the divergence is traced back to the dimensional mismatch of 3D hydrodynamic interactions and the colloidal particles moving only in 1D or 2D. Our results from theory are confirmed by Stokesian dynamics simulations and supported by light scattering observational data for particles at a fluid interface.