Crystal structure of ethyl 6-bromo-2-[(E)-2-phenyl-ethen-yl]quinoline-4-carboxyl-ate

T O Shrungesh Kumar; S Naveen; M N Kumara; K M Mahadevan; N K Lokanath

doi:10.1107/S2056989014028266

Crystal structure of ethyl 6-bromo-2-[(E)-2-phenyl-ethen-yl]quinoline-4-carboxyl-ate

Acta Crystallogr E Crystallogr Commun. 2015 Jan 17;71(Pt 2):o121. doi: 10.1107/S2056989014028266. eCollection 2015 Feb 1.

Authors

T O Shrungesh Kumar¹, S Naveen², M N Kumara³, K M Mahadevan⁴, N K Lokanath⁵

Affiliations

¹ Department of Chemistry, Kuvempu University, Jnanasahyadri, Shankaraghatta 577 451, India.
² Institution of Excellence, University of Mysore, Manasagangotri, Mysuru 570 006, India.
³ Department of Chemistry, Yuvaraja's College, University of Mysore, Mysuru 570 005, India.
⁴ Department of Chemistry, Kuvempu University, Jnanasahyadri, Shankaraghatta 577451, India.
⁵ Department of Studies in Physics, University of Mysore, Manasagangotri, Mysuru 570 006, India.

Abstract

In the title compound, C20H16BrNO2, the dihedral angle between the quinolone ring system mean plane (r.m.s. deviation = 0.018 Å) and the phenyl ring bridged by the ethynyl group, is 25.44 (14)°. There is an intra-molecular C-H⋯O hydrogen bond forming an S(6) ring motif. In the crystal, mol-ecules are linked via C-H⋯O hydrogen bonds forming chains propagating along the b-axis direction.

Keywords: crystal structure; hydrogen bonding; quinoline; quinoline-4-carboxylate.