Passive sampling for volatile organic compounds in indoor air-controlled laboratory comparison of four sampler types

Environ Sci Process Impacts. 2015 May;17(5):896-905. doi: 10.1039/c4em00560k. Epub 2015 Apr 10.

Abstract

This article describes laboratory testing of four passive diffusive samplers for assessing indoor air concentrations of volatile organic compounds (VOCs), including SKC Ultra II, Radiello®, Waterloo Membrane Sampler (WMS) and Automated Thermal Desorption (ATD) tubes with two different sorbents (Tenax TA and Carbopack B). The testing included 10 VOCs (including chlorinated ethenes, ethanes, and methanes, aromatic and aliphatic hydrocarbons), spanning a range of properties and including some compounds expected to pose challenges (naphthalene, methyl ethyl ketone). Tests were conducted at different temperatures (17 to 30 °C), relative humidities (30 to 90% RH), face velocities (0.014 to 0.41 m s(-1)), concentrations (1 to 100 parts per billion by volume [ppbv]) and sampling durations (1 to 7 days). The results show that all of the passive samplers provided data that met the success criteria (relative percent difference [RPD] ≤ 45% of active sample concentrations and coefficient of variation [COV] ≤ 30%) in the majority of cases, but some compounds were problematic for some samplers. The passive sampler uptake rates depend to varying degrees on the sampler, sorbent, target compounds and environmental conditions, so field calibration is advantageous for the highest levels of data quality.

Publication types

  • Comparative Study
  • Research Support, U.S. Gov't, Non-P.H.S.

MeSH terms

  • Air Pollutants / analysis*
  • Air Pollution, Indoor / analysis*
  • Environmental Monitoring / instrumentation*
  • Environmental Monitoring / methods
  • Volatile Organic Compounds / analysis*

Substances

  • Air Pollutants
  • Volatile Organic Compounds