Crystal structure of 1-meth-oxy-pyrene

Acta Crystallogr E Crystallogr Commun. 2015 Feb 28;71(Pt 3):o210-1. doi: 10.1107/S2056989015003783. eCollection 2015 Mar 1.

Abstract

The title compound, C17H12O, crystallized with three independent mol-ecules (A, B and C) in the asymmetric unit. In the crystal, the three independent mol-ecules are linked by π-π inter-actions [centroid-centroid distances = 3.551 (3)-3.977 (2) Å], which lead to the formation of trimers. Between the trimers there are a number of C-H⋯π inter-actions generating a laminar arrangement parallel to (010). The meth-oxy-methyl group in mol-ecule A is disordered over two sets of sites, with an occupancy ratio of 0.56 (9):0.44 (9).

Keywords: C—H⋯π inter­actions; crystal structure; organic photovoltaics; pyrene; π–π inter­actions.