Crystal structure of 4-methyl-N-[(4-methyl-pyridin-2-yl)carbamo-thioyl]-benzamide

Farook Adam; Nadiah Ameram; Naser Eltaher Eltayeb

doi:10.1107/S2056989015003412

Crystal structure of 4-methyl-N-[(4-methyl-pyridin-2-yl)carbamo-thioyl]-benzamide

Acta Crystallogr E Crystallogr Commun. 2015 Feb 28;71(Pt 3):315-7. doi: 10.1107/S2056989015003412. eCollection 2015 Mar 1.

Authors

Farook Adam¹, Nadiah Ameram¹, Naser Eltaher Eltayeb²

Affiliations

¹ School of Chemical Sciences, 11800, USM Pulau Pinang, Malaysia.
² College of Sciences and Arts, Rabigh, King Abdulaziz University, Saudi Arabia, and International University of Africa, Khartoum, Sudan.

Abstract

In the title compound, C15H15N3OS, the dihedral angle between the planes of the benzene and pyridine rings is 26.86 (9)°. Intra-molecular N-H⋯O and C-H⋯S hydrogen bonds both generate S(6) rings. The C=O and C=S bonds lie to opposite sides of the mol-ecule. In the crystal, inversion dimers linked by pairs of N-H⋯S hydrogen bonds generate R 2 (2)(8) loops.

Keywords: benzamide; crystal structure; hydrogen bonding; thiocarbonyl groups; thiourea compounds.