An intuitional hierarchical assembly of cluster-organic frameworks with a thickness of 1.97 nm from a discrete Co14 cluster

Fu-Ping Huang; Peng-Fei Yao; Hai-Ye Li; Qing Yu; He-Dong Bian; Hong Liang

doi:10.1039/c5cc01057h

An intuitional hierarchical assembly of cluster-organic frameworks with a thickness of 1.97 nm from a discrete Co14 cluster

Chem Commun (Camb). 2015 May 4;51(36):7598-601. doi: 10.1039/c5cc01057h.

Authors

Fu-Ping Huang¹, Peng-Fei Yao, Hai-Ye Li, Qing Yu, He-Dong Bian, Hong Liang

Affiliation

¹ Key Laboratory for the Chemistry and Molecular Engineering of Medicinal Resources (Ministry of Education of China), School of Chemistry and Pharmacy, Guangxi Normal University, Guilin, 541004, P. R. China. huangfp2010@163.com.

PMID: 25807458
DOI: 10.1039/c5cc01057h

Abstract

An intuitional hierarchical assembly, metaphorically referred to as a "blossom and yield fruit" process, from a discrete cluster {[Co14(CH3O)4(dpbt)6Cl12]·14CH3OH, ()} to 2D cluster organic frameworks {[Co14(CH3O)10(dpbt)6 Cl6]·12CH3OH, ()}, has been established. The magnetic ordering of was obviously improved compared with .