Reactivity and operational stability of N-Tailed TAMLs through kinetic studies of the catalyzed oxidation of orange II by H2 O2 : synthesis and X-ray structure of an N-phenyl TAML

Genoa R Warner; Matthew R Mills; Clarissa Enslin; Shantanu Pattanayak; Chakadola Panda; Tamas Kumar Panda; Sayam Sen Gupta; Alexander D Ryabov; Terrence J Collins

doi:10.1002/chem.201500719

Reactivity and operational stability of N-Tailed TAMLs through kinetic studies of the catalyzed oxidation of orange II by H2 O2 : synthesis and X-ray structure of an N-phenyl TAML

Chemistry. 2015 Apr 13;21(16):5993. doi: 10.1002/chem.201500719. Epub 2015 Mar 4.

Authors

Genoa R Warner¹, Matthew R Mills, Clarissa Enslin, Shantanu Pattanayak, Chakadola Panda, Tamas Kumar Panda, Sayam Sen Gupta, Alexander D Ryabov, Terrence J Collins

Affiliation

¹ Department of Chemistry, Carnegie Mellon University, 4400 Fifth Avenue, Pittsburgh, PA, 15213 (USA).

PMID: 25740016
DOI: 10.1002/chem.201500719

Abstract

Invited for the cover of this issue are Terrence J. Collins and co-workers at Carnegie Mellon University (USA) and the National Chemical Laboratory (India). The image depicts five generations of tetraamido macrocyclic ligand (TAML) activators, which are small molecule, full-functional mimics of oxidizing enzymes that arguably outperform the peroxidase enzymes they mimic. Read the full text of the article at 10.1002/chem.201406061.