Abstract
A series of iron complexes of chiral iminopyridine-oxazoline (IPO) ligands have been synthesized. The most sterically hindered iron catalyst exhibits excellent activity (up to 99% yield) and high enantioselectivity (up to 93% ee) in asymmetric hydrosilylation of aryl ketones.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Alcohols / chemical synthesis
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Alcohols / chemistry
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Catalysis
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Iron Compounds / chemical synthesis
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Iron Compounds / chemistry*
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Ketones / chemistry*
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Ligands
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Models, Molecular
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Molecular Structure
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Oxazoles / chemistry
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Pyridines / chemistry
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Stereoisomerism
Substances
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Alcohols
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Iron Compounds
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Ketones
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Ligands
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Oxazoles
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Pyridines