Mechanochemical ruthenium-catalyzed olefin metathesis

J Am Chem Soc. 2015 Feb 25;137(7):2476-9. doi: 10.1021/jacs.5b00151. Epub 2015 Feb 12.

Abstract

We describe the development of a mechanochemical approach for Ru-catalyzed olefin metathesis, including cross-metathesis and ring-closing metathesis. The method uses commercially available catalysts to achieve high-yielding, rapid, room-temperature metathesis of solid or liquid olefins on a multigram scale using either no or only a catalytic amount of a liquid.