Abstract
A novel family of heteronuclear Mn(IV)Ca-oxido complexes containing Mn(IV)Ca-oxido cuboidal moieties and reactive water molecules on Ca(2+) have been synthesized and characterized to mimic the oxygen-evolving complex (OEC) of photosystem II (PSII) in nature.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Biomimetic Materials / chemical synthesis
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Biomimetic Materials / chemistry*
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Calcium / chemistry*
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Coordination Complexes / chemical synthesis
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Coordination Complexes / chemistry*
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Manganese / chemistry*
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Models, Molecular
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Oxygen / chemistry*
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Photosystem II Protein Complex / chemistry*
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Water / chemistry
Substances
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Coordination Complexes
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Photosystem II Protein Complex
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Water
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Manganese
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Oxygen
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Calcium