1 Université de Rennes 1 - CNRS UMR 6226 "Institut des Sciences Chimiques de Rennes", Campus de Beaulieu, CS 74205, 35042 Rennes Cedex, France. yann.molard@univ-rennes1.fr.
We describe a new supramolecular approach combining host-guest and electrostatic interactions to design hybrid materials containing polyanionic bulky inorganic compounds and showing liquid crystalline properties.