Multiarylpolycarboxylate-mediated hybrid cobalt phosphate frameworks with supramolecular zeolitic topology and unusual I(2)O(2) connectivity

Qing-Rong Ding; Li-Ming Li; Lei Zhang; Jian Zhang

doi:10.1021/ic502895u

Multiarylpolycarboxylate-mediated hybrid cobalt phosphate frameworks with supramolecular zeolitic topology and unusual I(2)O(2) connectivity

Inorg Chem. 2015 Feb 16;54(4):1209-11. doi: 10.1021/ic502895u. Epub 2015 Jan 23.

Authors

Qing-Rong Ding¹, Li-Ming Li, Lei Zhang, Jian Zhang

Affiliation

¹ State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences , Fuzhou, Fujian 350002, P. R. China.

PMID: 25615541
DOI: 10.1021/ic502895u

Abstract

Two novel organic-inorganic hybrid frameworks containing multiarylpolycarboxylate linkers and cobalt phosphate layers, [H2DABCO]·[Co(HPO4)(bpdc)] (1) and [H2DABCO]3·[Co10(npa)3(PO4)6Cl2] (2), where bpdc = 4,4'-biphenyldicarboxylate, npa = 2,6-naphthalenedicarboxylate, and DABCO = 1,4-diazabicyclo[2.2.2]octane, have been solvothermally synthesized. Compound 1 features a 3D zeolite-like supramolecular network with ABW topology, and compound 2 is a 3D framework structure with unusual I(2)O(2) connectivity.