Spin canting, metamagnetism, and single-chain magnetic behaviour in a cyano-bridged homospin iron(II) compound

Dong Shao; Shao-Liang Zhang; Xin-Hua Zhao; Xin-Yi Wang

doi:10.1039/c4cc10003d

Spin canting, metamagnetism, and single-chain magnetic behaviour in a cyano-bridged homospin iron(II) compound

Chem Commun (Camb). 2015 Mar 14;51(21):4360-3. doi: 10.1039/c4cc10003d.

Authors

Dong Shao¹, Shao-Liang Zhang, Xin-Hua Zhao, Xin-Yi Wang

Affiliation

¹ State Key Laboratory of Coordination Chemistry, Collaborative Innovation Center of Advanced Microstructures, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, 210093, China. wangxy66@nju.edu.cn.

PMID: 25600433
DOI: 10.1039/c4cc10003d

Abstract

Spin canting, antiferromagnetic ordering, metamagnetism and single-chain magnetism were verified in a cyano-bridged Fe(II) compound synthesized from the pentagonal bipyramidal Fe(II) starting material in the presence of excessive BF4(-) anions.