Mesoporous alumina from colloidal biotemplating of Al clusters

Abstract

A simple and green synthesis route was disclosed for the achievement of mesoporous alumina microparticles employing polysaccharide nanoparticles (α-chitin nanorods) as templates. Pore textures can be tuned by the cationic alumina precursor. Compared to small cations, the use of Al13 and Al30 oxo-hydroxo clusters leads to better defined and elongated mesopores. Electron microscopy and spectroscopic ((13) C, (27) Al NMR, XPS) measurements demonstrated that this is related to the effective coating of α-chitin nanorods by these pre-condensed colloids.

Keywords: mesoporous materials; polysaccharides; self-assembly; spray-drying.