Edge-to-edge interaction between carbon nanotube-pyrene complexes and electrodes for biosensing and electrocatalytic applications

Phys Chem Chem Phys. 2015 Feb 14;17(6):4025-8. doi: 10.1039/c4cp05153j.

Abstract

We demonstrate here that the edge-to-edge interaction between carbon nanotubes (CNTs) and edge plane electrodes plays an important role in exposing a large proportion of the basal planes of the CNTs to allow enhanced π-π stacking of a pyrenyl compound and subsequent high density protein immobilization yielding large electrocatalytic currents.

Publication types

  • Research Support, N.I.H., Extramural

MeSH terms

  • Biosensing Techniques*
  • Catalysis
  • Electrochemical Techniques
  • Electrodes
  • Gold / chemistry
  • Immobilized Proteins / chemistry
  • Myoglobin / chemistry*
  • Nanotubes, Carbon / chemistry*
  • Oxidation-Reduction
  • Peroxidase / chemistry
  • Pyrenes / chemistry*

Substances

  • Immobilized Proteins
  • Myoglobin
  • Nanotubes, Carbon
  • Pyrenes
  • 1-pyrenebutyrate
  • Gold
  • Peroxidase